FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022744538> ?p ?o ?g. }

• W2022744538 endingPage "2649" @default.
• W2022744538 startingPage "2641" @default.
• W2022744538 abstract "Salts are present in most amorphous biomaterials such as dried or frozen solid foods, plant seeds, and bacterial spores, and in some pharmaceutical formulations. However, knowledge of how salts modulate the physical properties of amorphous solid sugars, a major component in these systems, is lacking. We have used phosphorescence of the triplet probe erythrosin B (Ery B) to monitor molecular mobility in amorphous sucrose films (dried against P(2)O(5)) containing the salts NaCl, MgCl(2), CaCl(2), NaAcetate, Na(3)Citrate, NaH(2)PO(4), or Na(2)HPO(4) at a mole ratio of 0.2:1 (salt/sucrose). All the salts examined, except NaH(2)PO(4), significantly increased the phosphorescence lifetime of Ery B over the temperature range from 5 to 100 degrees C. This increase is due to a reduction in the rate of collisional quenching of the triplet state due to interactions with the matrix, indicating that these salts decreased the matrix molecular mobility. NaAcetate, Na(3)Citrate, and Na(2)HPO(4) decreased mobility more than NaCl, CaCl(2), or MgCl(2), perhaps due to specific hydrogen bonding interactions between the anion and sucrose. Systematic variations in the probe emission lifetime across the excitation and emission bands at 25 degrees C indicate that there are sites of different mobilities within amorphous solid sucrose; this dynamic site heterogeneity was enhanced in the presence of the divalent cationic salts MgCl(2) and CaCl(2). These results suggest that salts may play a significant role in modulating the mobility, and thus the long-term stability, of amorphous biological matrixes." @default.
• W2022744538 created "2016-06-24" @default.
• W2022744538 creator A5022302895 @default.
• W2022744538 creator A5025961297 @default.
• W2022744538 date "2008-10-01" @default.
• W2022744538 modified "2023-09-25" @default.
• W2022744538 title "The effect of salts on molecular mobility in amorphous sucrose monitored by erythrosin B phosphorescence" @default.
• W2022744538 cites W1492626006 @default.
• W2022744538 cites W1547597445 @default.
• W2022744538 cites W182803988 @default.
• W2022744538 cites W1966122852 @default.
• W2022744538 cites W1966714050 @default.
• W2022744538 cites W1968066962 @default.
• W2022744538 cites W1977777199 @default.
• W2022744538 cites W1989492434 @default.
• W2022744538 cites W1990201535 @default.
• W2022744538 cites W1992996280 @default.
• W2022744538 cites W2001662606 @default.
• W2022744538 cites W2003228716 @default.
• W2022744538 cites W2004351146 @default.
• W2022744538 cites W2004620137 @default.
• W2022744538 cites W2011997684 @default.
• W2022744538 cites W2014717983 @default.
• W2022744538 cites W2017348702 @default.
• W2022744538 cites W2026910259 @default.
• W2022744538 cites W2032548284 @default.
• W2022744538 cites W2033189980 @default.
• W2022744538 cites W2034875509 @default.
• W2022744538 cites W2035428256 @default.
• W2022744538 cites W2035453522 @default.
• W2022744538 cites W2036901991 @default.
• W2022744538 cites W2041506075 @default.
• W2022744538 cites W2042110848 @default.
• W2022744538 cites W2045394347 @default.
• W2022744538 cites W2048887685 @default.
• W2022744538 cites W2056908906 @default.
• W2022744538 cites W2057569015 @default.
• W2022744538 cites W2059564760 @default.
• W2022744538 cites W2067796243 @default.
• W2022744538 cites W2068554247 @default.
• W2022744538 cites W2071250757 @default.
• W2022744538 cites W2071737639 @default.
• W2022744538 cites W2080911709 @default.
• W2022744538 cites W2082362921 @default.
• W2022744538 cites W2086058660 @default.
• W2022744538 cites W2086356224 @default.
• W2022744538 cites W2091570098 @default.
• W2022744538 cites W2093674335 @default.
• W2022744538 cites W2095051413 @default.
• W2022744538 cites W2098338244 @default.
• W2022744538 cites W2116033073 @default.
• W2022744538 cites W2122322942 @default.
• W2022744538 cites W2165234277 @default.
• W2022744538 cites W2170797104 @default.
• W2022744538 cites W2178509236 @default.
• W2022744538 cites W2189792302 @default.
• W2022744538 cites W331961242 @default.
• W2022744538 cites W4300128172 @default.
• W2022744538 doi "https://doi.org/10.1016/j.carres.2008.06.008" @default.
• W2022744538 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18771764" @default.
• W2022744538 hasPublicationYear "2008" @default.
• W2022744538 type Work @default.
• W2022744538 sameAs 2022744538 @default.
• W2022744538 citedByCount "11" @default.
• W2022744538 countsByYear W20227445382012 @default.
• W2022744538 countsByYear W20227445382014 @default.
• W2022744538 countsByYear W20227445382015 @default.
• W2022744538 countsByYear W20227445382016 @default.
• W2022744538 countsByYear W20227445382017 @default.
• W2022744538 countsByYear W20227445382018 @default.
• W2022744538 countsByYear W20227445382019 @default.
• W2022744538 crossrefType "journal-article" @default.
• W2022744538 hasAuthorship W2022744538A5022302895 @default.
• W2022744538 hasAuthorship W2022744538A5025961297 @default.
• W2022744538 hasConcept C112887158 @default.
• W2022744538 hasConcept C121332964 @default.
• W2022744538 hasConcept C121745418 @default.
• W2022744538 hasConcept C13965031 @default.
• W2022744538 hasConcept C178790620 @default.
• W2022744538 hasConcept C179104552 @default.
• W2022744538 hasConcept C181817918 @default.
• W2022744538 hasConcept C185592680 @default.
• W2022744538 hasConcept C2776371256 @default.
• W2022744538 hasConcept C2778597767 @default.
• W2022744538 hasConcept C32909587 @default.
• W2022744538 hasConcept C56052488 @default.
• W2022744538 hasConcept C62520636 @default.
• W2022744538 hasConcept C74884574 @default.
• W2022744538 hasConcept C8010536 @default.
• W2022744538 hasConcept C91881484 @default.
• W2022744538 hasConceptScore W2022744538C112887158 @default.
• W2022744538 hasConceptScore W2022744538C121332964 @default.
• W2022744538 hasConceptScore W2022744538C121745418 @default.
• W2022744538 hasConceptScore W2022744538C13965031 @default.
• W2022744538 hasConceptScore W2022744538C178790620 @default.
• W2022744538 hasConceptScore W2022744538C179104552 @default.
• W2022744538 hasConceptScore W2022744538C181817918 @default.
• W2022744538 hasConceptScore W2022744538C185592680 @default.

• next