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- W2022750185 abstract "A non-conventional Stark-sweep microwave spectrometer is designed and used to determine the linewidth parameter of a rotational line of the fluoroform molecule. The linewidth parameter for self-broadening of the J = 1–0, M = 0 rotational component of the ground vibrational state is determined over the pressure range of 2.6–6.5 Pa at a temperature of 300 K. An experimental method is presented to correct for modulation broadening, Doppler effect, wall collision, cell length and saturation broadening. The first derivative of the Lorentzian line shape is used to extract the absorption profile information (Δv) from the signals. The second order Stark effect is measured to calibrate the frequency scale. The linewidth parameter for the J = 1–0, M = 0 transition of the CHF3 molecule in the ground vibrational state is 268.0 ± 6.9 kHz/Pa." @default.
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- W2022750185 date "1996-06-01" @default.
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- W2022750185 title "Pressure broadening ofJ= 1–0 rotational line of the CHF3molecule in an electric field" @default.
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- W2022750185 doi "https://doi.org/10.1088/0031-8949/53/6/004" @default.
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