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- W2022751154 abstract "In a one-pot procedure, cyclic olefins such as 1, n = 1–3, can be transformed stereospecifically into the trans-substituted products 2 by chlorosulfenylation followed by alkylation with Lewis acidic organometallic reagents such as (CH3)2Zn/TiCl4 or (CH3)3Al. This reaction concept can be extended to trisubstituted olefins and α-chiral 1,2-disubstituted olefins, such as 3, high regio- and stereoselectivity being achieved in the latter case (formation of 4). The interplay of 1,2-asymmetric induction and trans stereospecificity leads to defined 1,3-stereorelationships." @default.
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- W2022751154 date "1987-10-01" @default.
- W2022751154 modified "2023-10-10" @default.
- W2022751154 title "Regio- and Stereoselective Carbosulfenylation of Olefins" @default.
- W2022751154 doi "https://doi.org/10.1002/anie.198710281" @default.
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