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• W2022751172 abstract "Three types of tetraazamacrocycles (1,4,8,11-tetraazacyclotetradecane, 1,4,8,12-tetraazacyclopentadecane, and 1,4,8,11-tetraazacyclotetradecane-5,7-dione) are grafted on the surface of phosphorus-containing dendrimers possessing P(S)Cl2 end groups (for generations 1 and 3: this corresponds to three and twelve macrocycles, respectively) and on the model compound PhCHNN(Me)P(S)Cl2. Depending on the nature of the macrocycle, the reaction induces the formation of five-membered rings (diazaphospholanes) or of six-membered rings (diazaphosphorinanes). The structure of the adducts is deduced from 13C NMR spectra and from X-ray diffraction studies of the reaction products (8, 9, 10) of the model compound." @default.
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• W2022751172 date "1999-07-01" @default.
• W2022751172 modified "2023-09-25" @default.
• W2022751172 title "Grafting of Tetraazamacrocycles on the Surface of Phosphorus-Containing Dendrimers" @default.
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• W2022751172 doi "https://doi.org/10.1002/(sici)1099-0690(199907)1999:7<1701::aid-ejoc1701>3.0.co;2-6" @default.
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