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• W2022754257 abstract "23Na-NMR probes the ionic composition in the immediate vicinity of the DNA molecule, in the presence of a series of quaternary ammonium bromides, of varying hydrocarbon chain length. The 23Na-NMR line shows two Lorentzian components, in accordance with quadrupolar relaxation theory for S = 32 nuclei under slow modulation. Deconvolution of the observed lineshape provides, in a reliable manner, the relative fraction of sodium counterions neutralizing the phosphate sites on DNA. This quantity (PBX)2 serves as an index of the relative affinities of various surfactant ions toward DNA, Na+ being the reference cation. The results are consistent with site binding of detergent ions to the nucleic acid, an interaction dominated by hydrophobic forces." @default.
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• W2022754257 date "1986-07-01" @default.
• W2022754257 modified "2023-09-24" @default.
• W2022754257 title "Displacement of sodium ions by surfactant ions from DNA A 23Na-NMR investigation" @default.
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• W2022754257 doi "https://doi.org/10.1016/0301-4622(86)80005-9" @default.
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