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- W2022755811 abstract "The treatment of nickel acetylacetonate with trimethylaluminium in the presence of tricyclohexylphosphine and nitrogen gives the dinitrogen complex {[(C6H11)3P]2Ni}2N2 (I). Intermediate methyl-nickel complexes can be isolated, and provide an insight into the mechanism of formation of (I). The nitrogen molecule is readily displaced to give [(C6H11)3P]2Ni. The reactions of this coordinatively unsaturated species are described. The structure of the dinitrogen complex has been determined by X-ray crystallography from 5977 reflections using an automatic diffractometer, and refined anisotropically for all 80 atoms to a final R-value of 11%. The molecule is shown to contain a linear Ni-N-N-Ni system in which the nitrogen molecule is enclosed in a cage formed by four of the cyclohexyl rings. The NN bond distance is 1.12 Å." @default.
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- W2022755811 date "1971-11-01" @default.
- W2022755811 modified "2023-10-17" @default.
- W2022755811 title "The preparation, reactions and structure of bis[bis(tricyclohexylphosphine)nickel] dinitrogen, {[(C6H11)3P]2Ni}2N2" @default.
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- W2022755811 doi "https://doi.org/10.1016/s0022-328x(00)80809-8" @default.
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