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- W2022755860 abstract "The pre-reduction of higher manganese oxides with post-consumer plastics as reductants has been investigated through experiments conducted in a laboratory scale horizontal tube furnace coupled with an off gas analysis through an online infrared (IR) gas analyser. Composite pellets of calcined manganese oxide (Mn3O4) with high density polyethylene (HDPE) (at C/O molar ratios of 1·5, 2·0 and 3·0) were heated rapidly to 1150°C under pure argon and the off gas was measured continuously by an IR analyser for CO, CO2 and CH4. The extent of reduction of Mn3O4 to MnO was calculated from a mass balance for removable oxygen. Solid reaction products were characterised by scanning electron microscopy and X-ray diffraction analysis was used to confirm the presence of MnO. The results indicate that Mn3O4 can be successfully pre-reduced to MnO using HDPE as a reductant. Gas analysis studies indicated that the polymer is first converted to CH4 which cracked partially or reformed to H2, C and/or CO. Reduction of Mn3O4 to MnO was subsequently effected by C, CO, H2 and the residual CH4." @default.
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- W2022755860 date "2013-02-01" @default.
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- W2022755860 title "Utilisation of post-consumer plastics in pre-reduction of higher manganese oxides in ferromanganese process" @default.
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- W2022755860 doi "https://doi.org/10.1179/1743281212y.0000000043" @default.
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