FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022755883> ?p ?o ?g. }

• W2022755883 endingPage "96" @default.
• W2022755883 startingPage "89" @default.
• W2022755883 abstract "In this work, nanoporous stainless steel (NPSS) prepared by anodization process was used as an electrode material to support noble metal-based catalysts. To decorate NPSS with Pd, copper was deposited into the pores of NPSS using pulsed electrodeposition, and followed by the galvanic replacement reaction between deposited Cu and PdCl2 solution. The surface morphology and composition of the prepared electrode were determined using scanning electron microscopy (SEM), atomic force microscopy (AFM) and energy dispersive X-ray spectroscopy (EDS). SEM and AFM images showed that self-organized nanopores with an average size of about 77 nm were formed on the stainless steel surface and then were successfully filled with Cu. Galvanic replacement resulted in the formation of a porous film with a high electrochemically active surface area (EASA = 173.4 cm2 mg−1) and greatly reducing Pd loading (29 μg cm−2). The EDS analysis revealed the presence of Cu and Pd in the prepared electrode (NPSS/Cu/Pd). Cyclic voltammetry, electrochemical impedance spectroscopy (EIS) and chronoamperometry techniques were used to investigate the electrochemical behavior of the NPSS/Cu/Pd electrode in alkaline media. It was found that the porosity of NPSS and the presence of Cu improve the long-term stability of the Pd film on the surface. The electrode exhibited a remarkable catalytic activity for electrooxidation of glycerol due to the large EASA. The obtained mass activity and onset potential for glycerol oxidation were 0.82 mA μgPd−1 and −0.35 V, respectively, which are acceptable as compared with those of palladium-carbon substrates. The results also indicated that the presence of Cu has a significant effect on the catalytic activity, the reaction kinetics and poisoning tolerance of the NPSS/Cu/Pd electrode. Accordingly, NPSS/Cu/Pd can be extended as a promising electrode for alcohol electrooxidation reactions in fuel cells and sensors." @default.
• W2022755883 created "2016-06-24" @default.
• W2022755883 creator A5017336302 @default.
• W2022755883 creator A5028477000 @default.
• W2022755883 creator A5056040998 @default.
• W2022755883 date "2014-08-01" @default.
• W2022755883 modified "2023-10-12" @default.
• W2022755883 title "Fabrication of a porous Pd film on nanoporous stainless steel using galvanic replacement as a novel electrocatalyst/electrode design for glycerol oxidation" @default.
• W2022755883 cites W1968765409 @default.
• W2022755883 cites W1982084046 @default.
• W2022755883 cites W1982976486 @default.
• W2022755883 cites W1985723151 @default.
• W2022755883 cites W1987417534 @default.
• W2022755883 cites W1989899789 @default.
• W2022755883 cites W1993188115 @default.
• W2022755883 cites W1994047197 @default.
• W2022755883 cites W1999624982 @default.
• W2022755883 cites W2001794283 @default.
• W2022755883 cites W2005872431 @default.
• W2022755883 cites W2009637334 @default.
• W2022755883 cites W2013564649 @default.
• W2022755883 cites W2013625230 @default.
• W2022755883 cites W2013647641 @default.
• W2022755883 cites W2014607415 @default.
• W2022755883 cites W2015280582 @default.
• W2022755883 cites W2016652985 @default.
• W2022755883 cites W2016664576 @default.
• W2022755883 cites W2019051304 @default.
• W2022755883 cites W2039560885 @default.
• W2022755883 cites W2046415846 @default.
• W2022755883 cites W2054446405 @default.
• W2022755883 cites W2054859639 @default.
• W2022755883 cites W2060127433 @default.
• W2022755883 cites W2062562495 @default.
• W2022755883 cites W2065388303 @default.
• W2022755883 cites W2067239914 @default.
• W2022755883 cites W2068102197 @default.
• W2022755883 cites W2074739958 @default.
• W2022755883 cites W2081980870 @default.
• W2022755883 cites W2117437107 @default.
• W2022755883 cites W2135022165 @default.
• W2022755883 cites W2138365534 @default.
• W2022755883 cites W2151838403 @default.
• W2022755883 cites W2163944539 @default.
• W2022755883 cites W4382393988 @default.
• W2022755883 doi "https://doi.org/10.1016/j.electacta.2014.05.041" @default.
• W2022755883 hasPublicationYear "2014" @default.
• W2022755883 type Work @default.
• W2022755883 sameAs 2022755883 @default.
• W2022755883 citedByCount "40" @default.
• W2022755883 countsByYear W20227558832015 @default.
• W2022755883 countsByYear W20227558832016 @default.
• W2022755883 countsByYear W20227558832017 @default.
• W2022755883 countsByYear W20227558832018 @default.
• W2022755883 countsByYear W20227558832019 @default.
• W2022755883 countsByYear W20227558832020 @default.
• W2022755883 countsByYear W20227558832021 @default.
• W2022755883 countsByYear W20227558832022 @default.
• W2022755883 countsByYear W20227558832023 @default.
• W2022755883 crossrefType "journal-article" @default.
• W2022755883 hasAuthorship W2022755883A5017336302 @default.
• W2022755883 hasAuthorship W2022755883A5028477000 @default.
• W2022755883 hasAuthorship W2022755883A5056040998 @default.
• W2022755883 hasConcept C127413603 @default.
• W2022755883 hasConcept C147789679 @default.
• W2022755883 hasConcept C159985019 @default.
• W2022755883 hasConcept C171250308 @default.
• W2022755883 hasConcept C17525397 @default.
• W2022755883 hasConcept C179104552 @default.
• W2022755883 hasConcept C185592680 @default.
• W2022755883 hasConcept C192562407 @default.
• W2022755883 hasConcept C26771246 @default.
• W2022755883 hasConcept C2777869211 @default.
• W2022755883 hasConcept C2778141235 @default.
• W2022755883 hasConcept C33989665 @default.
• W2022755883 hasConcept C42360764 @default.
• W2022755883 hasConcept C48940184 @default.
• W2022755883 hasConcept C52859227 @default.
• W2022755883 hasConcept C7040849 @default.
• W2022755883 hasConceptScore W2022755883C127413603 @default.
• W2022755883 hasConceptScore W2022755883C147789679 @default.
• W2022755883 hasConceptScore W2022755883C159985019 @default.
• W2022755883 hasConceptScore W2022755883C171250308 @default.
• W2022755883 hasConceptScore W2022755883C17525397 @default.
• W2022755883 hasConceptScore W2022755883C179104552 @default.
• W2022755883 hasConceptScore W2022755883C185592680 @default.
• W2022755883 hasConceptScore W2022755883C192562407 @default.
• W2022755883 hasConceptScore W2022755883C26771246 @default.
• W2022755883 hasConceptScore W2022755883C2777869211 @default.
• W2022755883 hasConceptScore W2022755883C2778141235 @default.
• W2022755883 hasConceptScore W2022755883C33989665 @default.
• W2022755883 hasConceptScore W2022755883C42360764 @default.
• W2022755883 hasConceptScore W2022755883C48940184 @default.
• W2022755883 hasConceptScore W2022755883C52859227 @default.
• W2022755883 hasConceptScore W2022755883C7040849 @default.
• W2022755883 hasLocation W20227558831 @default.
• W2022755883 hasOpenAccess W2022755883 @default.
• W2022755883 hasPrimaryLocation W20227558831 @default.

• next