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- W2022758212 abstract "Equilibrium constants, enthalpies, and entropies of formation of the shift reagent-substrate adducts were determined by the measurement of infrared spectra. Aniline was employed as substrate in most cases since its NH stretching absorption bands (νas) does not overlap with those of the adducts and suitable to estimate the amount of its free species quantitatively. A series of Ln(dpm)3 and Ln(fod)3 (where Ln=Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, and Yb) were used as shift reagents. The formation constants (K1 and K2), as well as ΔH, decrease in the increasing order of the atomic numbers of the central lanthanoid ions. The results were compared with those on some bis(β-diketonato) complexes of transition metal ions and discussed." @default.
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- W2022758212 date "1982-09-01" @default.
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- W2022758212 title "Thermodynamic Properties for the Adduct Formation of Some Shift Reagents with Aniline" @default.
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