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- W2022759051 abstract "Mossbauer effect and neutron-diffraction measurements have been made as a function of temperature on the exchange-enhanced superconductor ${mathrm{U}}_{6}$Fe. Non-Debye behavior is observed in the thermal mean-squared displacement of Fe with the Debye temperature changing from ${ensuremath{Theta}}_{f}$ensuremath{simeq}320 K above 100 K to ${ensuremath{Theta}}_{f}$ensuremath{simeq}400 K below 80 K. Changes in the Mossbauer shift below 100 K are attributed principally to electronic-structure changes of the Fe atom which lead to a small increase in the number of d electrons and a concomitant reduction in the number of s electrons. The neutron-diffraction results indicate a pronounced anisotropy in the unit-cell thermal expansion and below 100 K an anomalous temperature dependence for the c-axis component of the total Debye-Waller factor of Fe. These observations taken together imply that along the c axis, static displacements of the Fe atoms begin around 100 K and increase with decreasing temperature." @default.
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- W2022759051 date "1985-10-01" @default.
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- W2022759051 title "Phonon anomalies and local atomic displacements in the exchange-enhanced superconductor<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>U</mml:mi></mml:mrow><mml:mrow><mml:mn>6</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>Fe" @default.
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- W2022759051 doi "https://doi.org/10.1103/physrevb.32.4419" @default.
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