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- W2022763908 abstract "Abstract The energy-effect (ef) of the cyclic conjugation in individual hexagons was calculated for a number of total resonant sextet benzenoid hydrocarbons, with emphasis on the recently synthesized very large members of this class. The Clar picture (large ef in “full” hexagons and small ef in “empty” hexagons) is found to be obeyed without exception. Nevertheless, in very large benzenoids the ef-values of internal “full” hexagons are quite small, only slightly exceeding the ef-values of “empty” hexagons. The ef-values of all “empty” hexagons are nearly the same, whereas those of “full” hexagons vary to a great extent. The main structural feature influencing the ef-value of a “full” hexagon is the number of adjacent empty hexagons; general rules for this dependence are formulated." @default.
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- W2022763908 date "2000-10-01" @default.
- W2022763908 modified "2023-10-16" @default.
- W2022763908 title "Cyclic Conjugation in Total Resonant Sextet Benzenoid Hydrocarbons" @default.
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- W2022763908 doi "https://doi.org/10.1080/10406630008028147" @default.
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