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- W2022769949 abstract "Gaseous oxidation of carbon papers (CPs) decorated with carbon nanotubes (CNTs) with varying degrees of oxidation was conducted to investigate the influence of surface oxides on the performance of electrochemical capacitors fabricated with oxidized CNT/CP composites. The oxidation period was found to significantly enhance the O/C atomic ratio on the composites, and the increase in oxygen content upon oxidation is mainly contributed by the formation of CO and C–O groups. The electrochemical behavior of the capacitors was tested in 1 M H2SO4 within a potential of 0 and 1 V vs. Ag/AgCl. Both superhydrophilicity and specific capacitance of the oxidized CNT/CP composites were found to increase upon oxidation treatment. A linearity increase of capacitance with O/C ratio can be attributed to the increase of the population of surface oxides on CNTs, which imparts excess sites for redox reaction (pseudocapacitance) and for the formation of double-layer (double-layer capacitance). The technique of ac impedance combined with equivalent circuit clearly showed that oxidized CNT/CP capacitor imparts not only enhanced capacitance but also a low equivalent series resistance." @default.
- W2022769949 created "2016-06-24" @default.
- W2022769949 creator A5017465854 @default.
- W2022769949 creator A5034290509 @default.
- W2022769949 creator A5064018164 @default.
- W2022769949 date "2010-07-01" @default.
- W2022769949 modified "2023-09-23" @default.
- W2022769949 title "Influence of oxidation level on capacitance of electrochemical capacitors fabricated with carbon nanotube/carbon paper composites" @default.
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- W2022769949 doi "https://doi.org/10.1016/j.electacta.2010.04.085" @default.
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