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• W2022772287 abstract "A novel type of sol–gel-derived organic–inorganic molecular-based hybrid material with the two parts covalently linked together via Tb–O and Si–O bonds was synthesized. The organic component was obtained from a derivative of meta-aminobenzoic acid (MAB) which is modified by 3-(triethoxysilyl)-propyl isocyanate, and then the precursor is applied to coordinate to Tb3+ with the carboxyl group and its triethoxysilyl moiety is capable of undergoing polymerization or cross-linking reactions with TEOS (tetraethoxysilane). Accordingly, the final hybrid material is formed by a combination of hydrolysis and polycondensation processes of two ethoxy groups (both MAB-Si and TEOS). Ultraviolet absorption, phosphorescent and fluorescent spectra were used to investigate the photophysical properties of the hybrid material, which reveal that the triplet energy of modified meta-aminobenzoic acid matches with the emissive energy level of Tb3+. In this way, the intramolecular energy transfer process took place within this molecular-based hybrid and a strong green emission of Tb3+ was achieved." @default.
• W2022772287 created "2016-06-24" @default.
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• W2022772287 date "2004-01-01" @default.
• W2022772287 modified "2023-10-10" @default.
• W2022772287 title "Novel luminescent terbium molecular-based hybrids with modified meta-aminobenzoic acid covalently bonded with silica" @default.
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• W2022772287 doi "https://doi.org/10.1039/b402667e" @default.
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