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- W2022777729 abstract "The successive rates of substitution of acid groups (Cl, NO2) in trans-dichlorodiammine-palladium(II), dichloroethylenediaminepalladium(II), cis- and trans-dinitrodiamminepalladium(II) by a variety of reagents of widely different nucleophilic character like water, aniline, glycine, pyridine, thiourea, and hydroxide ion were fully investigated by following the change in conductance of the solutions with time. The results indicated that the reactions are of the SN2 type and the rates decrease in the following sequence of the incoming groups: hydroxide ion > thiourea > pyridine > glycine > aniline > water. This is also more or less the (decreasing) order of nucleophilic character of these groups. The great dependence of the rate on the nucleophilic character of the incoming group, coupled with the fact that the cis-form was usually found to react faster than the corresponding trans-compound, indicates that the trans-effect is of no significance in the complexes of palladium(II). Moreover, the fact that trans-dinitrodiamminepalladium(II) reacts much more slowly than the corresponding dichloro complex shows that π-bonding activation of the trans position does not occur in these complexes." @default.
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- W2022777729 date "1958-08-01" @default.
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- W2022777729 title "Kinetics and mechanism of substitution in complexes of palladium(II)" @default.
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- W2022777729 doi "https://doi.org/10.1016/0022-1902(58)80030-5" @default.
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