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• W2022779949 abstract "The evolution of the understanding of the mass transport phenomena in solids and liquids allows for the unification of phenomenological models. The central Darken problem is considered from the choice of the coordinate axes for diffusion, i.e. the definition of this mode of motion and the method of diffusion displacement is defined and measured. Euler's and Liouville theorems are used extensively in the analysis. The formula is derived for volume density conservation, i.e. the volume continuity equation. This fundamental formula defines the volume-fixed frame of reference in the multicomponent solid, gas and liquid solutions. The volume-fixed frame of reference is self-consistent with the foundations of linear irreversible thermodynamics, except that is recognises the need to add volume density to the usual list of extensive physical properties undergoing transport in every continuum. Proposed modifications are self-consistent with the literature dating back to Onsager, the experiments of Kirkendall, their interpretation by Darken and recent generalized formulations. It will be shown that the method can be used in mechano-chemistry and electro-mechano-chemistry." @default.
• W2022779949 created "2016-06-24" @default.
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• W2022779949 date "2009-02-01" @default.
• W2022779949 modified "2023-10-16" @default.
• W2022779949 title "Diffusion, drift and their interrelation through volume density" @default.
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• W2022779949 doi "https://doi.org/10.1080/14786430802620732" @default.
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