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- W2022781619 abstract "The dehydrogenation/hydrogenation properties of LiBH4-xMg(OH)2 were systematically investigated. The results show that the LiBH4-0.3Mg(OH)2 composite possesses optimal dehydrogenation properties: approximately 9.6 wt% of hydrogen is released via a stepwise reaction with an onset temperature of 100 °C. In the range of 100–250 °C, a chemical reaction between LiBH4 and Mg(OH)2 first occurs to give rise to the generation of LiMgBO3, MgO and H2. From 250 to 390 °C, the newly developed LiMgBO3 reacts with LiBH4 to form MgO, Li3BO3, LiH, B2O3 and Li2B12H12 with hydrogen release. From 390 to 450 °C, the decomposition of LiBH4 and Li2B12H12 proceeds to release additional hydrogen and to form LiH and B. A further hydrogenation experiment indicates that the dehydrogenated LiBH4-0.3Mg(OH)2 sample can take up 4.7 wt% of hydrogen at 450 °C and 100 bar of hydrogen with good cycling stability, which is superior to the pristine LiBH4." @default.
- W2022781619 created "2016-06-24" @default.
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- W2022781619 date "2014-05-01" @default.
- W2022781619 modified "2023-10-16" @default.
- W2022781619 title "Reversible hydrogen storage behavior of LiBH4–Mg(OH)2 composites" @default.
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- W2022781619 doi "https://doi.org/10.1016/j.ijhydene.2014.03.137" @default.
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