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- W2022782818 abstract "The synthesis of an azide containing PNA monomer is described. The monomer was incorporated into two PNA sequences for the purpose of synthesizing an intercalating fluorophore-labeled PNA and a metal binding hairpin using a solid phase copper catalyzed azide-alkyne Huisgen cycloaddition (CuAAC). Click chemistry was performed using 2-ethynylfluorene or 1-ethynylpyrene to add a fluorophore to the PNA, which were tested for their ability to recognize an abasic site on a DNA target. A PNA hairpin possessing azide monomers at each termini was synthesized and reacted with 2-ethynylpyridine to form a hairpin that is stabilized by Ni2+." @default.
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- W2022782818 date "2013-01-01" @default.
- W2022782818 modified "2023-10-09" @default.
- W2022782818 title "A solid-phase CuAAC strategy for the synthesis of PNA containing nucleobase surrogates" @default.
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- W2022782818 doi "https://doi.org/10.4161/adna.23982" @default.
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