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- W2022786593 abstract "Gas chromatography was coupled with plasma mass spectrometry with a microplasma ion source for negative ion detection. The ion source, which was kept inside the high vacuum chamber of the mass spectrometer, was a rigid fused silica capillary tube containing a capacitively coupled radiofrequency helium plasma. This made the setup quite simple: eliminating the sampler–skimmer pressure-reducing interface traditionally used in plasma mass spectrometry. The present study describes the utilization of halogen-selective negative ion detection. A high selectivity of fluorine to hydrocarbon compounds (3 × 103), and a highly sensitive detection for F, Cl, Br, and I (0.13–12 pg s−1), were obtained. The mechanisms of negative ion formation and breakdown were discussed in conjunction with the results that were achieved." @default.
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- W2022786593 date "2000-01-01" @default.
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- W2022786593 title "Capillary gas chromatography coupled with negative ionization microplasma mass spectrometry for halogen-selective detection" @default.
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- W2022786593 doi "https://doi.org/10.1039/a904211c" @default.
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