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- W2022787991 abstract "Pt(COD) 2 (COD = cyclo-octadiene) has proved to be a versatile starting compound for the synthesis of platinum triangulo -cluster compounds, many of which could not be synthesised by other routes. The reaction of Pt(COD) 2 with CNC 8 H 9 and PCy 3 (Cy = cyclo-hexyl) resulted in the formation of cluster compounds that could not be obtained by substitution reactions based on related triangulo cluster compounds. The structure of [Pt 3 (μ-CNC 8 H 9 ) 3 (PCy 3 ) 3 ] has been determined by a single crystal X-ray diffraction study, and sheds light on the steric interactions in this class of cluster compound. The interconversion reactions of the cluster compounds synthesised by this route have been studied." @default.
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- W2022787991 date "1993-12-01" @default.
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- W2022787991 title "Synthesis and interconversion of triangulo cluster compounds of platinum with isocyanide and phosphine ligands" @default.
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- W2022787991 doi "https://doi.org/10.1016/0022-328x(93)83378-9" @default.
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