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- W2022789364 abstract "A simple, particle size-independent spectrometric method has been developed for the multi-element determination of wear metals in used engine oil. A small aliquot (0.5 ml) of an acid-digested oil sample is spotted onto a C-18 solid phase extraction disk to form a uniform thin film. The dried disk is then analyzed directly by energy dispersive X-ray fluorescence spectrometry. This technique provides a homogeneous and reproducible sample surface to the instrument, thus overcoming the typical problems associated with uneven particle size distribution and sedimentation. As a result, the method provides higher precision and accuracy than conventional methods. Furthermore, the disk sample may be stored and re-analyzed or extracted at a later date. The signals arising from the spotted disks, and the calibration curves constructed from them, are stable for at least 2 months. The limits of detection for Fe, Cu, Zn, Pb, and Cr are 5, 1, 4, 2, and 4 μg g−1, respectively. Recoveries of these elements from spiked oil samples range from 92 to 110%. The analysis of two standard reference materials and a used oil sample produced results comparable to those found by inductively coupled plasma atomic emission spectrometry." @default.
- W2022789364 created "2016-06-24" @default.
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- W2022789364 date "2003-03-10" @default.
- W2022789364 modified "2023-10-10" @default.
- W2022789364 title "Determination of wear metals in engine oil by mild acid digestion and energy dispersive X-ray fluorescence spectrometry using solid phase extraction disks" @default.
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- W2022789364 doi "https://doi.org/10.1016/s0039-9140(02)00580-5" @default.
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