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- W2022790188 abstract "N,N,N′,N′-Tetramethylethylenediamine (TMED) reacts with Et2O:BF3 to give the highly insoluble adduct TMED:2 BF3. TMED also reacts with representative monoalkylboranes to form both TMED-monoalkylborane (TMED: BH2R) and the corresponding bis-adducts (TMED:2BH2R). These are air stable and can be stored for long periods. Boron trifluoride rapidly removes TMED from these adducts, liberating the corresponding monoalkylboranes. This procedure provides a new valuable means of storing monoalkylboranes as their stable adducts with TMED, with rapid regeneration of the parent monoalkylboranes as desired." @default.
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- W2022790188 date "1978-08-01" @default.
- W2022790188 modified "2023-10-16" @default.
- W2022790188 title "Molecular addition compounds of N,N,N′,N′-tetramethylethylenediamine with boron trifluoride and monoalkylboranes" @default.
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- W2022790188 doi "https://doi.org/10.1016/s0022-328x(00)84886-x" @default.
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