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- W2022792639 abstract "Es gibt mehrere Hinweise über unerwartet hohe Korrosionsraten des Eisens in schwach alkalischen Medien in Nähe des Gleichgewichtes. Diese Vorgänge sind thermodynamisch nur verständlich, wenn komplexe Korrosionsprodukte vorliegen. Ferner wird verständlich. daß ein kathodischer Korrosionsschutz weniger durch Annäherung an das Gleichgewicht als durch Deckschichteffekte wirksam wird. Überlegungen zum Aktiv-Passiv-Verhalten zeigen. daß zur Deutung des Aktivierungspotentials thermodynamische Betrachtungen ohne Erfolg bleiben müssen. Some aspects of the corrosion of iron in alkaline solutions and associated fundamental questions There are some indications of iron corrosion in alkaline solutions with unexpectedly high rates. These reactions can be understood thermodynamically only in terms of the formation of complex compounds, e.g. with hydroxide ions. Furthermore, it is demonstrated that the effect of cathodic protection is more established by the formation of protective films than by the shift into the equilibrium state. Considerations about the active passive behaviour show that thermodynamical explanations of the activation potential (Flade potential) must fail." @default.
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- W2022792639 date "1983-06-01" @default.
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- W2022792639 title "Bemerkungen zur Alkalischen Korrosion von Eisen und zu den damit verbundenen Grundlagenfragen" @default.
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- W2022792639 doi "https://doi.org/10.1002/maco.19830340603" @default.
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