Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022793501> ?p ?o ?g. }
- W2022793501 endingPage "14151" @default.
- W2022793501 startingPage "14137" @default.
- W2022793501 abstract "Initial rate studies have revealed dramatic acceleration in aerobic Pd(II)-catalyzed C−H olefination reactions of phenylacetic acids when mono-N-protected amino acids are used as ligands. In light of these findings, systematic ligand tuning was undertaken, which has resulted in drastic improvements in substrate scope, reaction rate, and catalyst turnover. We present evidence from intermolecular competition studies and kinetic isotope effect experiments that implies that the observed rate increases are a result of acceleration in the C−H cleavage step. Furthermore, these studies suggest that the origin of this phenomenon is a change in the mechanism of C−H cleavage from electrophilic palladation to proton abstraction." @default.
- W2022793501 created "2016-06-24" @default.
- W2022793501 creator A5041386747 @default.
- W2022793501 creator A5045820274 @default.
- W2022793501 creator A5080816898 @default.
- W2022793501 date "2010-09-20" @default.
- W2022793501 modified "2023-10-18" @default.
- W2022793501 title "Ligand-Accelerated C−H Activation Reactions: Evidence for a Switch of Mechanism" @default.
- W2022793501 cites W1963978672 @default.
- W2022793501 cites W1964262574 @default.
- W2022793501 cites W1964407022 @default.
- W2022793501 cites W1964792825 @default.
- W2022793501 cites W1965396770 @default.
- W2022793501 cites W1966363887 @default.
- W2022793501 cites W1969142039 @default.
- W2022793501 cites W1969470048 @default.
- W2022793501 cites W1969544904 @default.
- W2022793501 cites W1969605542 @default.
- W2022793501 cites W1970234358 @default.
- W2022793501 cites W1970756071 @default.
- W2022793501 cites W1972643104 @default.
- W2022793501 cites W1973051136 @default.
- W2022793501 cites W1975369435 @default.
- W2022793501 cites W1976533925 @default.
- W2022793501 cites W1977031456 @default.
- W2022793501 cites W1977120818 @default.
- W2022793501 cites W1978890358 @default.
- W2022793501 cites W1980934047 @default.
- W2022793501 cites W1981916864 @default.
- W2022793501 cites W1982018824 @default.
- W2022793501 cites W1982298201 @default.
- W2022793501 cites W1985357742 @default.
- W2022793501 cites W1985768828 @default.
- W2022793501 cites W1986741599 @default.
- W2022793501 cites W1987207730 @default.
- W2022793501 cites W1987808027 @default.
- W2022793501 cites W1988057900 @default.
- W2022793501 cites W1989697974 @default.
- W2022793501 cites W1991200342 @default.
- W2022793501 cites W1992593125 @default.
- W2022793501 cites W1994390276 @default.
- W2022793501 cites W1995102570 @default.
- W2022793501 cites W1996650596 @default.
- W2022793501 cites W1997105281 @default.
- W2022793501 cites W1997770703 @default.
- W2022793501 cites W1998089003 @default.
- W2022793501 cites W1998854104 @default.
- W2022793501 cites W1999286141 @default.
- W2022793501 cites W1999535730 @default.
- W2022793501 cites W1999589112 @default.
- W2022793501 cites W2000441241 @default.
- W2022793501 cites W2001173848 @default.
- W2022793501 cites W2002565158 @default.
- W2022793501 cites W2003577473 @default.
- W2022793501 cites W2003640875 @default.
- W2022793501 cites W2003876494 @default.
- W2022793501 cites W2004561964 @default.
- W2022793501 cites W2004867175 @default.
- W2022793501 cites W2006144480 @default.
- W2022793501 cites W2006383333 @default.
- W2022793501 cites W2006758620 @default.
- W2022793501 cites W2008217595 @default.
- W2022793501 cites W2008616263 @default.
- W2022793501 cites W2010101793 @default.
- W2022793501 cites W2010584571 @default.
- W2022793501 cites W2011475011 @default.
- W2022793501 cites W2012757735 @default.
- W2022793501 cites W2012780101 @default.
- W2022793501 cites W2014264279 @default.
- W2022793501 cites W2015550201 @default.
- W2022793501 cites W2016755677 @default.
- W2022793501 cites W2016792667 @default.
- W2022793501 cites W2016896228 @default.
- W2022793501 cites W2017384210 @default.
- W2022793501 cites W2017732168 @default.
- W2022793501 cites W2019568660 @default.
- W2022793501 cites W2020546190 @default.
- W2022793501 cites W2022696812 @default.
- W2022793501 cites W2023213954 @default.
- W2022793501 cites W2023243840 @default.
- W2022793501 cites W2024476636 @default.
- W2022793501 cites W2024536147 @default.
- W2022793501 cites W2025493688 @default.
- W2022793501 cites W2027303432 @default.
- W2022793501 cites W2027866078 @default.
- W2022793501 cites W2030212357 @default.
- W2022793501 cites W2031567023 @default.
- W2022793501 cites W2031623053 @default.
- W2022793501 cites W2032510498 @default.
- W2022793501 cites W2033336148 @default.
- W2022793501 cites W2036497439 @default.
- W2022793501 cites W2036504954 @default.
- W2022793501 cites W2037032992 @default.
- W2022793501 cites W2038146277 @default.
- W2022793501 cites W2038452922 @default.
- W2022793501 cites W2038974680 @default.
- W2022793501 cites W2038999038 @default.
- W2022793501 cites W2044349280 @default.