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- W2022795431 abstract "A kinetic isotope effect (kD/kH) of 7.4 has been found for the reaction of chlorosilylene with trimethysilane (Me3SiD vs Me3SiH). Such a value can be accounted for by theoretical modelling, but only if an internal rearrangement of the initially form complex is included in the mechanism. This provides the first concrete evidence for such complexes." @default.
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- W2022795431 date "2011-07-29" @default.
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- W2022795431 title "Dramatic Isotope Effect in the Reaction of ClSiH with Trimethylsilane-1-d: Experimental Evidence for Intermediate Complexes in Silylene Si–H(D) Insertion Reactions" @default.
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- W2022795431 doi "https://doi.org/10.1021/om200411x" @default.
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