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• W2022797172 endingPage "158" @default.
• W2022797172 startingPage "151" @default.
• W2022797172 abstract "Abstract The diffraction study of bis(5-bromo-N-m-tolylsalicylaldiminate)copper(II) shows the copper atom in a centrosymmetric position and the two ligands displayed trans to each other in a planar environment. Two additional weak interactions due to Br atoms (Jahn-Teller effect) of neighboring units complete the coordination sphere, CuBr = 3.662(2) A , so that the comple is formally a polynuclear two-dimensional species. On the contrary, bis(3,5-dibromo-N-p-tolylsalicylaldiminate(copper(II) is mononuclear and shows only the two ligands coordinated and the geometry is distorted ‘tetrahedral’. The distortion is due to intramolecular repulsion interactions. Electronic spectra of these two compounds show a single asymmetric band at 700 nm for the former, and two bands located at 650 and 850 nm for the latter. Both compounds are monoclinic, space group P2 1 /c with a = 9.919(2) A , b = 10.965(2) A , c = 12.283(2) A , β = 105.88(1)°, Z = 2 for the former, and a = 13.290(2) A , b = 12.195(2) A , c = 17.891(2) A , β = 105.38(1)°, Z = 4 for the latter." @default.
• W2022797172 created "2016-06-24" @default.
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• W2022797172 creator A5026912676 @default.
• W2022797172 creator A5037540170 @default.
• W2022797172 creator A5061036054 @default.
• W2022797172 date "1998-01-01" @default.
• W2022797172 modified "2023-09-23" @default.
• W2022797172 title "Planar or tetrahedral coordination in copper(II) complexes induced by bromo substitution" @default.
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• W2022797172 doi "https://doi.org/10.1016/s0020-1693(97)05571-0" @default.
• W2022797172 hasPublicationYear "1998" @default.
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