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- W2022804130 abstract "The molecular arrangements in liquid state may be characterized by assignement of the number of nearest neighbors on each molecule, and distances between two nearest neighbors. The assumption is made on the distribution of distances r between the two nearest neighbors which does not take a definite value as in the crystalline state but is distributed over the region of [r(1+δ), r(1−δ)]. The partition function and state equation are deduced under these assumptions using proper values of δ expected by X-ray diffraction on liquid argon. The critical constants for a simple liquid are determined which agree well with experimental values. The condition for the equilibrium between liquid and solid crystalline states is obtained on the basic assumptions that the essential differences of liquid and solid states consist in the difference of values of δ and the number of nearest neighbors around each molecule. The calculated melting temperature, volume and entropy inerements by fusion and pressure dependences of these fusion parameters agree well with experimental values." @default.
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- W2022804130 date "1950-06-01" @default.
- W2022804130 modified "2023-09-25" @default.
- W2022804130 title "Fusion and State Equation of Simple Liquids. II. Critical Data and Fusion Parameters" @default.
- W2022804130 doi "https://doi.org/10.1246/bcsj.23.240" @default.
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