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- W2022806476 abstract "The kinetics of the exchange between 56Mn-labelled oxides: MnO, Mn2O3, Mn3O4 and three forms of the dioxide, and solutions of ions Mn+ (M=metal, n=2 or 3) showed a slower step following a faster step, presumably involving a surface layer. The rate and extent of the exchange depend on the type and form of the oxide rather than its BET surface area. The exchange kinetics as well as the kinetics of other physico-chemical processes offer suitable characterization methods for these oxide powders. The three battery-active dioxides were also characterized by the rates of reduction by hydrazine hydrate or by Cr3+ ion solutions as well as the rate of catalysing the decomposition of H2O2. In the case of Mn2O3 and Mn3O4, they were characterized by the 56Mn-exchange process, the rate of oxidation of Cr3+ ion solutions and the rate of leachingMn(III) from the solid by pyrophosphate. The results of these studies are compared with the reported surface area of the powders." @default.
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- W2022806476 date "1999-08-01" @default.
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- W2022806476 title "Radiochemical and physicochemical characterization of manganese oxides" @default.
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- W2022806476 doi "https://doi.org/10.1016/s0039-6028(99)00170-3" @default.
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