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- W2022806487 abstract "The T1,2←S0 phorescence excitation spectrum of acetophenone has been observed in a crystal at 4.2 K. The observed tangled vibronic structure is a manifestation that two states of different orbital types, 3ππ* and 3nπ*, lie close to each other. For the first time, the spectrum has been vibrationally analyzed in terms of the crude adiabatic Born-Oppenheimer vibronic states. The calculation is advanced via the following steps: (1) to assume appropriate zero-order vibronic level functions of both electronic excited states in the energy region 0–1000 cm−1 above the T1 phosphorescent origin level, (2) to take into account two different perturbations of vibronic and environmental interactions, (3) to establish a secular equation with two adjustable parameters for the evaluation of the off-diagonal matrix elements, (4) to diagonalize the equation after allocating appropriate values to the parameters, (5) to simulate the T←S spectrum, (6) to compare the simulation spectrum with the observed, (7) to revise several ..." @default.
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- W2022806487 date "1985-07-01" @default.
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- W2022806487 title "Vibrational Analysis of Tangled Spectra. I. The Crystal Phase T←S Spectra of Acetophenone" @default.
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