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- W2022807623 abstract "Terminal alkynes are easily transformed into enantiomerically enriched compounds containing tertiary and quaternary carbon atoms. Sulfinylation followed by reduction (or alkylation) and hydrocyanation of the resulting vinyl sulfoxides with Et2AlCN provides nitriles bearing the chiral center, which can in turn undergo reaction to form the desired products (see reaction scheme). Tol=4-tolyl. Supporting information for this article is available on the WWW under http://www.angewandte.com or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W2022807623 date "2001-07-02" @default.
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- W2022807623 title "Stereoselective Hydrocyanation of Alkenyl Sulfoxides as a Method to Highly Enantiomerically Enriched Compounds with Tertiary and Quaternary Chiral Carbon Atoms" @default.
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- W2022807623 doi "https://doi.org/10.1002/1521-3773(20010702)40:13<2507::aid-anie2507>3.0.co;2-r" @default.
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