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• W2022808729 startingPage "207" @default.
• W2022808729 abstract "Reaction of 1,2-diisocyanobenzene with [Fe2Cp2(CO)3NCMe] (Cp=η-cyclopentadienyl) (1:2) yields the tetranuclear complex [{Fe2CP2(CO)2(μ-CO)}2(μ4-CNC6H4NC)] (2) which in solution appears to exist as a mixture of cis and trans isomeric forms. 2 may be diprotonated to yield [{Fe2Cp2(CO)3}2(μ4-CN(H)C6H4N(H)C)](BF4)2 (3), monoalkylated to give [{Fe2Cp2(CO)3}2(μ4-CN(R)C6H4NC)]BF4 (R=Me (4), Et (5)) and oxidatively cleaved with one molecule of I2 to give [FeCp(I)(CO)2] and the asymmetric species [{Fe2Cp2(CO)3}CNC6H4NC{FeCp(I)CO}] (6). In addition, 2 acts as a bidentate ligand towards the Lewis acidic metal halides FeCl2, PdCl2, ZnCl2, ZnI2 and CdI2 giving rise to surprisingly stable pentanuclear supercomplexes (7a–e) which have been characterized by elemental analyses and IR and NMR (1H, 13C) spectra. Of 7c, an X-ray structure analysis has been carried out which for the first time assesses the μ3-(C,C,N) bridging mode of isocyanide in a non-cluster molecule. The most striking stereochemical features are the various gross distortions and deviations from more idealized geometries which are undoubtedly governed by the steric overcrowding in the molecule." @default.
• W2022808729 created "2016-06-24" @default.
• W2022808729 creator A5003256884 @default.
• W2022808729 creator A5058585608 @default.
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• W2022808729 date "1993-10-01" @default.
• W2022808729 modified "2023-09-23" @default.
• W2022808729 title "A bis(μ-isocyanide diiron) complex as chelating ligand towards iron(II), palladium(II), zinc(II) and cadmium(II). X-ray structural assessment of a novel isocyanide bridging mode" @default.
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• W2022808729 doi "https://doi.org/10.1016/s0020-1693(00)92327-2" @default.
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