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• W2022809069 abstract "The ZEKE photoelectron spectrum of methyl formate in a supersonic jet was recorded using multibunch VUV synchrotron radiation. The adiabatic ionisation potential is determined to 87 390 cm−1 (10.835 eV). Three yet unobserved normal modes of the electronic ground state (ν10, ν11, and ν12) and the progression of a mode previously assigned to ν4 are observed. Ab initio calculations reveal a large Duschinsky rotation upon ionisation of three modes implying that the ν4 progression corresponds to an OCO-antisymmetrical stretch motion. The finer vibrational structure observed on the electronic ground state above 1500 cm−1 is considerably perturbed due to the anharmonicity of the potential surface." @default.
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• W2022809069 date "1994-02-01" @default.
• W2022809069 modified "2023-09-27" @default.
• W2022809069 title "Zero kinetic energy (ZEKE) photoelectron spectrum and coincident mass spectra of methyl formate" @default.
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• W2022809069 doi "https://doi.org/10.1002/bbpc.19940980207" @default.
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