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- W2022824641 abstract "Abstract Up to 1985 only the two fluorophosphaalkenes F 3 CPCF 2 and HPCF 2 were known in the literature [1]. Since then we were able to prepare by several new routes a variety of derivatives A to G in gram quantities and to study their properties. This report will describle some specific properties of fluoro and trifluoromethylphosphaalkenes, recently discovered in our laboratory, e.g. • 1,3-fluorine shift: F 3 CPC(CF 3 ) 2 F 3 CP(F)C(CF 3 )CF 2 , • formation of unusual ylids by 1,2-fluorine transfer (reaction of A , D or E with PMe 3 ), • application of compounds of type G as equivalent of PC-NR 2 , • use of compounds D or F as (η 1 -μ 2 )4e donor in binuclear complexes [(CO) 5 Cr] 2 L ." @default.
- W2022824641 created "2016-06-24" @default.
- W2022824641 creator A5036694523 @default.
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- W2022824641 date "1991-09-01" @default.
- W2022824641 modified "2023-09-27" @default.
- W2022824641 title "Fluorine - an element of surprise in phosphaalkene chemistry" @default.
- W2022824641 cites W1939249557 @default.
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- W2022824641 doi "https://doi.org/10.1016/s0022-1139(00)83747-1" @default.
- W2022824641 hasPublicationYear "1991" @default.
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