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- W2022829529 abstract "Mixtures of cyanogen and nitrous oxide diluted in argon were shock heated to measure the ratio of the rate constants for (3)NCO+O→CO+NO and (4)NCO+M→N+CO+M. The diagnostic was narrow-line absorption of NCO at 440.479 nm using a remotely located cw ring dye laser source. By varying the mole fraction of nitrous oxide in the initial mixture and conducting otherwise identical experiments, we inferred at 2240°K k3k4=103.54(+0.34, −0.37). Utilizing a recent determination of k3 and previous measurements of the ratio k3k4, we recommend over the temperature range 2150 ⩽ T ⩽ 2400°K k4=1016.8T−0.5exp[−24000/T] cm3/mole/s [×2.3, ×0.4]. An additional mixture of cyanogen, oxygen, hydrogen, and nitrous oxide diluted in argon was shock heated and NCO was monitored to infer the rate constant for (5)NCO+H→CO+NH and the ratio k6k7: (6)C2N2+H→CN+HCN,(7)CN+H2→HCN+H. We found near 1490°K k5=1013.73(+0.42,−0.27) cm3/mole/s, and k6k7=0.81(+0.89, −0.47). These experiments also led to an estimate of the rate constant for (8)NCO+H2→HNCO+H, with the result, near 1490°K, k8≃1012.1(+0.4,−0.7) cm3/mole/s." @default.
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- W2022829529 date "1984-12-01" @default.
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- W2022829529 title "High temperature kinetics of NCO" @default.
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- W2022829529 doi "https://doi.org/10.1016/0010-2180(84)90113-5" @default.
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