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- W2022831359 abstract "Abstract Natural product mayamycin is the first example in the angucycline class featuring a C ‐glycoside linkage at the C5‐position of the benz[ a ]anthracenone core with remarkable biological activities. We successfully synthesized the two retrosynthetic fragments, but found that the final C ‐glycosylation did not occur. Alternatively, an A‐ring saturated aglycon was prepared, but the proposed C ‐glycosylation still did not proceed. Finally, a simplified substrate was used and the subsequent C ‐glycosylation went through smoothly, giving a two‐ring less analogue of mayamycin." @default.
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- W2022831359 date "2013-01-01" @default.
- W2022831359 modified "2023-09-25" @default.
- W2022831359 title "Synthesis Study toward Mayamycin" @default.
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- W2022831359 doi "https://doi.org/10.1002/cjoc.201201084" @default.
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