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- W2022834302 endingPage "4646" @default.
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- W2022834302 abstract "The mechanism of nickel-catalyzed couplings of an enone, alkyne, and organozinc has been studied. Adducts of the substrates with nickel(0) have been isolated and characterized, and their reactivity was examined. A potential intermediate was demonstrated to not be kinetically competent in catalytic cyclizations. A computational approach employing the B3LYP density functional method and the 6-31G(d) basis set was used to examine mechanistic possibilities that were consistent with experimental observations, and a modified mechanism for the catalytic cyclizations was formulated. The newly proposed mechanism involves production of an active catalyst that involves a novel interaction between Ni(0) and dimethylzinc." @default.
- W2022834302 created "2016-06-24" @default.
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- W2022834302 creator A5072645125 @default.
- W2022834302 creator A5082427922 @default.
- W2022834302 date "2004-09-01" @default.
- W2022834302 modified "2023-10-17" @default.
- W2022834302 title "Combined Experimental and Computational Investigation of the Mechanism of Nickel-Catalyzed Three-Component Addition Processes" @default.
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