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- W2022837514 abstract "2-O-Unprotected and 2-deoxy-2,3-dehydro-neuraminic acid derivatives 2, 4, and 10 exhibit enhanced acceptor properties at their 8-hydroxy group in sialylation reactions with phosphite 5 as donor; yet, mainly (10) or exclusively (2, 4) β-glycoside bond formation was observed. The 3-phenylthionocarbonate group as stereodirecting auxiliary group in the sialyl donor 11 led with 10 as acceptor to exclusive formation of α(2–8)-linked disaccharide." @default.
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- W2022837514 date "1997-09-01" @default.
- W2022837514 modified "2023-10-16" @default.
- W2022837514 title "8-O-Sialylation of neuraminic acid acceptor reactivity and anomeric stereocontrol" @default.
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