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- W2022841728 abstract "The Diels–Alder reaction between 2,5-dimethylfuran and vinylene carbonate was studied, both from an experimental and a theoretical point of view. The system was shown to slowly reach a thermodynamic equilibrium, characterized by the almost exclusive formation of the exo isomer. We rationalized these results by a comparison with classical systems involving maleic anhydride, and highlighted the different reactivity of vinylene carbonate as a dienophile. Finally, a preparative scale synthesis of pure exo isomer 4, a potentially useful synthon, ensued from this work." @default.
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- W2022841728 date "2010-01-01" @default.
- W2022841728 modified "2023-10-18" @default.
- W2022841728 title "Diels–Alder reaction of vinylene carbonate and 2,5-dimethylfuran: kinetic vs. thermodynamic control" @default.
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- W2022841728 doi "https://doi.org/10.1039/b9nj00536f" @default.
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