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- W2022851210 abstract "Solution-reaction calorimetry was used to determine the standard molar enthalpy of formation at 298.15 K of crystalline [M(S2CNPrn2)2](M = Zn, Cd or Hg): –440.68 ± 2.85, –396.71 ± 2.60 and –240.50 ± 2.40 kJ mol–1, respectively. The enthalpies of sublimation, 147 ± 2, 199 ± 1 and 200 ± 2 kJ mol–1, were estimated by means of differential scanning calorimetry. From the standard molar enthalpies of formation of the gaseous chelates, –294 ± 4, –198 ± 3 and –41 ± 3 kJ mol–1, the homolytic 182 ± 3, 154 ± 3 and 102 ± 3 kJ mol–1 and heterolytic 745 ± 3, 681 ± 3 and 709 ± 3 kJ mol–1 mean metal-sulfur bond enthalpies were calculated. The homolytic enthalpies decrease from zinc to mercury and are dependent on the nature of the radical attached to the nitrogen of the ligand." @default.
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- W2022851210 date "1992-01-01" @default.
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- W2022851210 title "Thermochemical features of di-n-propyldithiocabamate chelates of zinc-group elements" @default.
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- W2022851210 doi "https://doi.org/10.1039/dt9920001235" @default.
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