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• W2022860135 startingPage "257" @default.
• W2022860135 abstract "Electron–cation geminate recombination in isooctane has been reinvestigated by femtosecond spectroscopy. The observed recombination kinetics are well-fit by a single exponential decay (τ = 400 ± 40 fs) and exhibit a significant hydrogen/deuterium kinetic isotope effect. The kinetics are not affected by varying the incident intensity or by exciting the recombining electrons with a high power 800 nm pulse. These observations strongly suggest that the recombination rate is not limited by diffusive motion of the ions to form a contact ion pair, but rather by the electron transfer reaction rate between the ions in a contact ion pair." @default.
• W2022860135 created "2016-06-24" @default.
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• W2022860135 date "2005-02-01" @default.
• W2022860135 modified "2023-09-26" @default.
• W2022860135 title "The mechanism of electron–cation geminate recombination in liquid isooctane" @default.
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• W2022860135 doi "https://doi.org/10.1016/j.cplett.2005.01.015" @default.
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