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• W2022871885 startingPage "412" @default.
• W2022871885 abstract "A time of flight mass spectrometer coupled with a cluster formation and reaction source is employed to study the reactivity of cationic vanadium oxide clusters (VmOn +) toward ethylene (C2H4) in the gas phase. The cationic vanadium oxide clusters with m=1-10 and n=1-26 (depending on m) are generated by reaction of laser ablation created vanadium plasma with O2 in a supersonic expansion and then reacted with the ethylene in a flow tube reactor. Hydrogen atoms are attached in most of the oxygen saturated clusters (2n5m) in our experimental condition. The reactivity of VmOn + toward C2H4 is usually higher than that of hydrogen containing clusters, VmOnH2x +. Larger clusters show less reactivity than smaller ones. Most of the observed products are in the forms of VmOnC2H4 + and VmOnH2xC2H4 + due to direct association. C2H4 clustering products ((C2H4)n +, n=2-6) are also observed." @default.
• W2022871885 created "2016-06-24" @default.
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• W2022871885 date "2007-08-01" @default.
• W2022871885 modified "2023-10-11" @default.
• W2022871885 title "Reaction of Cationic Vanadium Oxide Clusters with Ethylene in a Flow Tube Reactor" @default.
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• W2022871885 doi "https://doi.org/10.1088/1674-0068/20/04/412-418" @default.
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