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- W2022876879 abstract "Abstract A theory of multiple-ion jumps is proposed to explain the large apparent jump distances which have been calculated from high field conduction in glasses. An analysis of published data on correlation coefficients suggests that multiple ion jumps up to about four ions at a time may occur in single-alkali glasses. In mixed-alkali glasses such processes are shown to be less probable. Measurements of high field conductivity were made on both single- and mixed-alkali glasses, using blown membranes between N /10 acid solutions. The onset of departures from Ohm's law occurred at fields of about 10 7 V m −1 from which a jump distance of about 25–30 A is calculated. This is too large for the proposed multiple-ion jump processes suggested, and, furthermore, the high field currents followed the Poole-Frenkel (PF) law. An alternative theory is given in which the PF law is derived for ionic migration: shallow coulombic potential basins are assumed to be distributed throughout the volume of the glass, owing to non-bridging oxygens whose charge is not balanced by cations on adjacent sites." @default.
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- W2022876879 date "1978-03-01" @default.
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- W2022876879 title "Ionic jump processes and high field conduction in glasses" @default.
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- W2022876879 doi "https://doi.org/10.1016/0022-3093(78)90021-2" @default.
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