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- W2022882105 abstract "Though In(III)-catalyzed C-C bond formations are common, this report highlights the first In(0)-catalyzed C-C bond-forming process. Ketone allylations can be achieved using allylboronates in the presence of as little as 3 mol% of In(0). Interestingly, aqueous medium is required and the reaction is performed solely in water. Using α-methylallylboronate gives exclusively α-addition to the ketones in good yields and moderate syn/anti selectivity. A preliminary result for the asymmetric version of this reaction is reported using a chiral bis(oxazoline) ligand." @default.
- W2022882105 created "2016-06-24" @default.
- W2022882105 date "2008-12-18" @default.
- W2022882105 modified "2023-09-26" @default.
- W2022882105 title "Indium(0)-Catalyzed Allylations of Ketones in Water" @default.
- W2022882105 doi "https://doi.org/10.1055/s-0028-1087398" @default.
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