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- W2022882510 abstract "Kinetic deuterium isotope effects have been determined for the reaction of the cyclic amidine base DBU [1,5-diazabicyclo(5,4,0)undec-5-ene] with the carbon acid 4-nitrophenylnitromethane in toluene solution from –5 to +25°C. The isotopic rate ratio for the forward reaction (kHf/kDf) at 25°C is 13.3 ± 1.2; this is large enough to suggest an appreciable tunnelling correction. The activation enthalpies are strikingly low, both for proton and deuteron transfer: ΔH‡Hf= 2.0 ± 0.2 kcal mol–1(8.4 ± 0.8 kJ mol–1) and ΔH‡Df= 3.6 ± 0.3 kcal mol–1(15.1 ± 1.3 kJ mol–1). The interpretation of these results is discussed." @default.
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- W2022882510 date "1978-01-01" @default.
- W2022882510 modified "2023-09-26" @default.
- W2022882510 title "Kinetic isotope effect in the reaction of 4-nitrophenylnitro-methane with the cyclic amidine base DBU [1,5-diazabicyclo(5,4,0)undec-5-ene]" @default.
- W2022882510 doi "https://doi.org/10.1039/f19787402065" @default.
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