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- W2022886988 abstract "Contact-angle measurements for water, glycerol, formamide, di-iodomethane and bromoform on fluorite plates covered with a film of oleate are made. Using the contact-angle values, the Lifshitz-van der Waals component and the electron-acceptor parameter of the surface free energy of the fluorite/oleate film are calculated. On the basis of the contact-angle measurements and the calculations done, it is found that at low equilibrium oleate concentration the surface free energy of the fluorite/oleate film comes close to the value for paraffin, however at high oleate concentration, the surface of the fluorite/oleate film can interact with the adherent phase not only by Lifshitz-van der Waals forces but also by acid-base forces. It results from a hydration process which takes place at the highest sodium oleate concentrations. It is stated that the considerable decrease of the fluorite/oleate- film-water interfacial free energy at oleate species concentration higher than 87.1 mg/dm3 can also result from electrostatic interactions across the interface." @default.
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- W2022886988 date "1993-10-01" @default.
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- W2022886988 title "The influence of oleate adsorption at the fluorite/water interface on fluorite surface free energy" @default.
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- W2022886988 doi "https://doi.org/10.1016/0169-4332(93)90013-2" @default.
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