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- W2022888356 abstract "The investigation of the systems A O-TL2O3-ACO3 has allowed three new oxycarbonates A4TL2CO3O6 to be synthesized for A = Ca, Sr, Ba. A study of the system SrO-TL2O3, under the same conditions, i.e., in sealed tubes, has not been able to detect the well-known oxide Sr4Tl2O7. An XRD and ED study of these oxycarbonates leads to a tetragonal I-centered cell with a ≈ 5Å and c ≈ 18Å, previously obtained for Sr4Tl2O7. The detailed ED study of the oxycarbonate Ca4Tl2CO3O6 has shown the following features: (i) there exist very weak extra reflections leading to an orthorhombic supercell a' = 2a, b' = a, c ' = c, and (ii) streaks are observed along c* correlated to a disordered stacking of some (001) layers. The powder XRD and HREM investigation of this phase shows that its structure consists of distorted rock salt-type layers interleaved with layers of carbonate groups. The close relationships between this structure and that of the 1201 layered cuprates are discussed." @default.
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- W2022888356 date "1995-05-01" @default.
- W2022888356 modified "2023-10-14" @default.
- W2022888356 title "New Thallium Oxycarbonates Built Up from Rock Salt Layers: A4TL2CO3O6 (A = Ca, Sr, Ba)" @default.
- W2022888356 doi "https://doi.org/10.1006/jssc.1995.1221" @default.
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