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- W2022889568 abstract "Ether transfer methodology is capable of stereoselectively generating 1,3-diol mono- and diethers in good yield. Surprisingly, allylic and benzylic substrates provide none of the desired products when exposed to previously optimized conditions of iodine monochloride. Herein, second-generation activation conditions for ether transfer have been developed that circumvents undesired side reactions for these substrates. The application of this chemistry to the enantioselective synthesis of diospongins A and B has now been accomplished." @default.
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- W2022889568 date "2013-09-01" @default.
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- W2022889568 title "Concise enantioselective synthesis of diospongins A and B" @default.
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- W2022889568 doi "https://doi.org/10.1016/j.tet.2013.05.081" @default.
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