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• W2022892726 abstract "1,1-Bis(1″,2″,3″,4″,5″-pentamethylferrocen-1′-yl)ethene (6) was synthezised as a prototype of two metallocenes that are bridged by the sp2-carbon center of a vinylidene group. Starting from 6-N,N-dimethylamino-6-methylfulvene, the iron-containing intermediates were a pentamethylferrocenyl-substituted fulvene and an ethene that was geminally disubstituted by a Cp anion and a pentamethylferrocenyl moiety. Besides other methods, the ferrocenes were characterized by NMR spectroscopy including full signal assignment. The bimetallic compound 6 showed moderate interactions between the two ferrocenes in the cyclic voltammogram (ΔE1/2=150 mV). According to X-ray crystal structure analysis compound 6 is a twisted molecule; the vinylidene moiety and the Cps of the neighboring ferrocenes are not coplanar." @default.
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• W2022892726 date "1999-02-01" @default.
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• W2022892726 title "1,1-Bis(1″,2″,3″,4″,5″-pentamethylferrocen-1′-yl)ethene" @default.
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• W2022892726 doi "https://doi.org/10.1016/s0022-328x(98)00924-3" @default.
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