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- W2022893613 abstract "Abstract The complex formation of uranium(VI) with glycerol 1-phosphate was determined by potentiometric titration, and TRLFS spectroscopy. Two complexes with a metal-to-ligand stoichiometry of 1:1 and 1:2 were found by potentiometry in the pH range 3–8, and the stability constants were calculated for I =0.1 M (NaClO 4 ) and T =25 °C to be log β 11 =6.23±0.09 for UO 2 (C 3 H 7 O 3 PO 3 ) and log β 12 =10.22±0.13 for UO 2 (C 3 H 7 O 3 PO 3 ) 2 2− . The TRLFS spectra at pH=4 show an increase of the fluorescence intensity, connected with a red shift of the emission spectra. But contrary to the potentiometric measurements only the 1:1 complex UO 2 (C 3 H 7 O 3 PO 3 ) could be detected under the specific experimental conditions. The main fluorescence emission bands and the lifetime of this complex were determined. The complex stability constant at I =0.1 M (NaClO 4 ) and T =25 °C was calculated to be log β 11 =6.15±0.05." @default.
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- W2022893613 date "2004-06-01" @default.
- W2022893613 modified "2023-09-26" @default.
- W2022893613 title "Complexation of uranium(VI) with glycerol 1-phosphate" @default.
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- W2022893613 doi "https://doi.org/10.1016/j.poly.2004.04.022" @default.
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