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- W2022896799 abstract "Abstract Ammonium bromide crystals doped with Cu 2+ ions and grown from a basic solution have been studied at temperatures ranging from 4.2 to 300 K with Q-band EPR. The NH 4 Br : Cu 2+ crystals grown under these conditions contain CuBr 4 (NH 3 ) 2 2− paramagnetic centres showing sensibility to NH 4 Br phase transitions. A detailed EPR study of this centre was conducted to determine some spin Hamiltonian parameters for the first time, as the NH 4 Br : Cu 2+ crystals undergo phase transitions below room temperature. This study showed that the paramagnetic centre exhibited tetragonal symmetry at room temperature and below 78 K (a vestige of orthorhombic symmetry remained in this region), while at 78 K T" @default.
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- W2022896799 date "2001-09-01" @default.
- W2022896799 modified "2023-09-28" @default.
- W2022896799 title "EPR of the CuBr4(NH3)22− paramagnetic centre in ammonium bromide" @default.
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- W2022896799 doi "https://doi.org/10.1016/s0921-4526(01)00496-3" @default.
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