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- W2022900776 abstract "Rates of the possible cross-disproportionation reactions of these radicals relative to their rates of cross-combination, have been measured and are compared with auto-disproportionation-to-combination ratios which were also determined for these radicals. Selected asymmetric azo alkanes RNNR′ and mixtures of symmetric azo alkanes RNNR were used as sources of the desired free radicals. Photolysis under relatively high intensity conditions (ca. 10 18 quanta/cm 2 s) at room temperature generated the radicals in sufficiently high concentration that competing reactions of abstraction and condensation were negligible. Both the alkene and alkane products of disproportionation reactions were measured to ensure the completeness of the mechanism invoked and to increase the accuracy of the results. Δ(Me, Et) = 0.036 ± 0.003, Δ(Me, Pr n ) = 0.058 ± 0.004, Δ(Me, Pr s ) = 0.163 ± 0.005, Δ(Et, Pr n ) = 0.065 ± 0.005, Δ(Et, Pr s ) = 0.18 ± 0.008, Δ(Pr n , Et) = 0.057 ± 0.005, Δ(Pr s , Et) = 0.12 ± 0.01, and Δ(Pr n , Pr s ) = 0.41 ± 0.02 were deduced from the data, where Δ(A, B) refers to the ratio of disproportionation producing the alkane product derived from A to the combination of A with B." @default.
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- W2022900776 date "1967-10-15" @default.
- W2022900776 modified "2023-09-27" @default.
- W2022900776 title "Disproportionation and combination reactions of simple alkyl radicals: methyl, ethyl, <i>n</i>-propyl, and isopropyl" @default.
- W2022900776 doi "https://doi.org/10.1139/v67-379" @default.
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